Ion Chromatography
Ion Chromatography (IC) is a technique for quantitative analysis of major anions, such as fluoride, chloride, bromide, nitrate, nitrite, sulphate and phosphate in the parts-per-billion (ppb) range. Concentration of organic acids can also be measured through ion chromatography.
The chromatographic process separates the different ions within the sample based on their affinity to the ion exchanger. The concentration of an anions is measured by the change in conductivity as the species passes through the detector.
Aqueous samples do not require any specific preparation, but solid samples, for example rubber and polymer samples or other organic matrices require oxygen flask combustion procedure before being analysed.
Rubber Consultants have used IC for analysis of Total Sulphur, Combined Sulphur, Total Chloride, Total Bromide, Migration studies, Leachable anions and Extractable anions.
Applications
- Determination of Total Sulphur in cured rubber compound
- Determination of Combined Sulphur in condoms
- Fluoride Extractives under Code of Federal Regulations (CFR) Title 21 177.2400 (d)
- Total Chloride to determine the amount of Polychloroprene in Polychloroprene/PTFE blend
- Determination of leached adipic (hexanedioic) acid in pressurised metered dose inhalers (pMDIs)
- Determination of leached polybutylene (PBT) oligomers in pressurised metered dose inhalers (pMDIs)
- Determination of short chain organic acids in raw rubber